Organic Chemicals
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Quality Factory Supply 99% Pure 4,4'-DINITROBIPHENYL 1528-74-1 with Efficient Delivery
- Molecular Formula: C12H8 N2 O4
- Molecular Weight: 244.207
- Melting Point: 242°C
- Refractive Index: 1.6360 (estimate)
- Boiling Point: 418.1 °C at 760 mmHg
- Flash Point: 208.8 °C
- PSA： 91.64000
- Density: 1.368 g/cm3
- LogP: 4.21640
1528-74-1 Relevant articles
Homocoupling of Organostannanes Catalyzed by Iminophosphine-Palladium
Shirakawa, Eiji,Murota, Yasubumi,Nakao, Yoshiaki,Hiyama, Tamejiro
, p. 1143 - 1144 (1997)
An iminophosphine-palladium complex has ...
-
Newkome,Taylor
, p. 1362 (1979)
-
Immobilization of copper(II) in organic-inorganic hybrid materials: A highly efficient and reusable catalyst for the classic Ullmann reaction
Wu, Qiang,Wang, Lei
, p. 2007 - 2012 (2008)
The immobilization of copper(II) in orga...
Carbon-carbon bond formation via homocoupling reaction of substrates with a broad diversity in water using Pd(OAc)2 and agarose hydrogel as a bioorganic ligand, support and reductant
Firouzabadi, Habib,Iranpoor, Nasser,Kazemi, Faezeh
, p. 94 - 99 (2011)
In this study, we have presented a new c...
Water-dispersible and magnetically separable gold nanoparticles supported on a magnetite/s-graphene nanocomposite and their catalytic application in the Ullmann coupling of aryl iodides in aqueous media
Dabiri, Minoo,Shariatipour, Monire,Kazemi Movahed, Siyavash,Bashiribod, Sahareh
, p. 39428 - 39434 (2014)
Water-dispersible sulfonated graphene (s...
DAB-Cy as an inexpensive and effective ligand for palladium-catalyzed homocoupling reaction of aryl halides
Ma, Ning,Duan, Zheng,Wu, Yangjie
, p. 5709 - 5712 (2006)
A novel catalytic system of PdCl2(CH3CN)...
Au-Pd bimetallic nanoparticles supported on a high nitrogen-rich ordered mesoporous carbon as an efficient catalyst for room temperature Ullmann coupling of aryl chlorides in aqueous media
Karimi, Babak,Barzegar, Hossein,Vali, Hojatollah
, p. 7155 - 7158 (2018)
An ionic liquid derived highly nitrogen-...
Facile construction of biaryls by homocoupling of aryl halides
Hajipour, Abdol R.,Abrishami, Fatemeh
, p. 227 - 231 (2013)
-
Band Gap Modification of TiO2 Nanoparticles by Ascorbic Acid-Stabilized Pd Nanoparticles for Photocatalytic Suzuki–Miyaura and Ullmann Coupling Reactions
Feizpour, Fahimeh,Jafarpour, Maasoumeh,Rezaeifard, Abdolreza
, (2019)
In this study, synthesis, characterizati...
An effective and environment-friendly system for Cu NPs@RGO-catalyzed C-C homocoupling of aryl halides or arylboronic acids in ionic liquids under microwave irradiation
Zhao, Hongyan,Mao, Guijie,Han, Huatao,Song, Jinyi,Liu, Yang,Chu, Wenyi,Sun, Zhizhong
, p. 41108 - 41113 (2016)
As an outstanding mesh catalyst support,...
Direct homocoupling of aryl halides catalyzed by palladium
Penalva, Vincent,Hassan, Jwanro,Lavenot, Laurence,Gozzi, Christel,Lemaire, Marc
, p. 2559 - 2560 (1998)
Symmetrical functionnalized biaryls are ...
PdAu alloy nanoparticles supported on nitrogen-doped carbon black as highly active catalysts for Ullmann coupling and nitrophenol hydrogenation reactions
Han, Fengyan,Xia, Jiawei,Zhang, Xinglong,Fu, Yongsheng
, p. 17812 - 17823 (2019)
Noble metal-based catalysts have been pr...
Synthesis of gold nanoparticles decorated on sulfonated three-dimensional graphene nanocomposite and application as a highly efficient and recyclable heterogeneous catalyst for Ullmann homocoupling of aryl iodides and reduction of p-nitrophenol
Dabiri, Minoo,Kashi, Seyede Razie Banifatemi,Lehi, Noushin Farajinia,Bashiribod, Sahareh
, (2018)
Gold nanoparticles were decorated onto s...
Palladium-catalyzed arylation of α,α-difluoro-allylic-β-hydroxyester
Fang, Xiang,Yang, Xueyan,Yang, Xianjin,Zhao, Min,Chen, Guorong,Wu, Fanhong
, p. 8231 - 8234 (2006)
The aryl-substituted α,α-difluoro-allyli...
Au25 nanocluster-catalyzed Ullmann-type homocoupling reaction of aryl iodides
Li, Gao,Liu, Chao,Lei, Yu,Jin, Rongchao
, p. 12005 - 12007 (2012)
The Au25(SR)18/CeO2 nanocluster catalyst...
Thiazole-based non-symmetric NNC-palladium pincer complexes as catalytic precursors for the Suzuki-Miyaura C-C coupling
Camacho-Espinoza, Martín,Reyes-Deloso, Alberto,Toscano, R. Alfredo,Penieres-Carrillo, J. Guillermo,López-Cortés, José G.,Ortega-Alfaro, M. Carmen,Ortega-Jiménez, Fernando
, p. 12967 - 12978 (2019)
We report an efficient synthesis of new ...
DEDIAZONIATION OF ARENEDIAZONIUM SALT WITH TRIVALENT PHOSPHORUS COMPOUNDS BY ONE-ELECTRON TRANSFER MECHANISM
Yasui, Shinro,Fujii, Masayuki,Kawano, Chihiro,Nishimura, Yukihiro,Ohno, Atsuyoshi
, p. 5601 - 5604 (1991)
Trivalent phosphorus compounds, tripheny...
-
Schultz
, (1874)
-
-
Davey,Latter
, p. 264 (1948)
-
Highly water-dispersible magnetite-supported Pd nanoparticles and single atoms as excellent catalysts for Suzuki and hydrogenation reactions
Guarnizo,Angurell,Muller,Llorca,Seco,Rossell,Rossell
, p. 68675 - 68684 (2016)
The molecule 4-(diphenylphosphino)benzoi...
Tandem intramolecular silylformylation and silicon-assisted cross-coupling reactions. Synthesis of geometrically defined α,β-unsaturated aldehydes
Denmark, Scott E.,Kobayashi, Tetsuya
, p. 5153 - 5159 (2003)
The palladium- and copper-catalyzed cros...
RHODIUM CATALYZED REDUCTION OF ARYL IODIDES WITH A MODEL OF NAD(P)H
Yasui, Shinro,Nakamura, Kaoru,Ohno, Atsuyoshi
, p. 377 - 378 (1984)
Aryl iodides are reduced to the correspo...
Recyclable and reusable Pd(OAc)2/PPh3/PEG-2000 system for homocoupling reaction of arylboronic acids under air without base
Xia, Jianhui,Cheng, Mingzhu,Chen, Qiurong,Cai, Mingzhong
, p. 113 - 116 (2015)
A stable and efficient Pd(OAc)2/PPh3/PEG...
A new protocol for the one-pot synthesis of symmetrical biaryls
Nising, Carl F.,Schmid, Ulrike K.,Nieger, Martin,Braese, Stefan
, p. 6830 - 6833 (2004)
Biaryls play an important role in modern...
Suzuki Coupling of Chiral 1,1′-Binaphthyl Systems - New Synthetic Routes to Functionalize the 2- and 2,2′-Positions
Schilling, Birgit,Kaufmann, Dieter E.
, p. 701 - 709 (1998)
1,1′-Binaphthyl derivatives 1-5, substit...
-
Hodgson,Ward
, p. 127,128 (1947)
-
Electroreductive palladium-catalysed Ullmann reactions in ionic liquids: Scope and mechanism
Pachon, Laura Duran,Elsevier, Cornells J.,Rothenberg, Gadi
, p. 1705 - 1710 (2006)
A room-temperature catalytic alternative...
Icosahedral gold-platinum alloy nanocrystals in hollow silica: A highly active and stable catalyst for Ullmann reactions
Wu, Xiaoli,Tan, Longfei,Chen, Dong,Meng, Xianwei,Tang, Fangqiong
, p. 539 - 541 (2014)
Icosahedral Au-Pt alloy nanocrystals are...
Pd/TEMPO-catalyzed electrooxidative synthesis of biaryls from arylboronic acids or arylboronic esters
Mitsudo, Koichi,Shiraga, Takuya,Kagen, Daisuke,Shi, Deqing,Becker, James Y.,Tanaka, Hideo
, p. 8384 - 8388 (2009)
A facile electrooxidative method for syn...
The β-cyclodextrin decorated with palladium nanoparticles without pretreatment: An efficient heterogeneous catalyst for biaryls synthesis
Feiz, Afsaneh,Loni, Masood,Naderi, Soheila,Bazgir, Ayoob
, (2018)
β-Cyclodextrin decorated with palladium ...
A comparative homocoupling reaction of aryl halides using monomeric orthopalladated complex of 4-methoxybenzoylmethylenetri-phenylphosphorane under conventional and microwave irradiation conditions
Hajipour, Abdol R.,Karami, Kazem,Tavakoli, Ghazal
, p. 567 - 576 (2011)
The activity of [Pd(C6H4CH2NH 2-K2-C-N)P...
Pd-catalyzed oxidative homocoupling of arylboronic acids in aqueous ethanol at room temperature
Zhou, Zhonggao,Hu, Qiaosheng,Du, Ziyi,Xue, Jun,Zhang, Shiyong,Xie, Yongrong
, p. 940 - 943 (2012)
The authors demonstrate for the first ti...
Absolute Configuration Assignment from Optical Rotation Data by Means of Biphenyl Chiroptical Probes
Vergura, Stefania,Scafato, Patrizia,Belviso, Sandra,Superchi, Stefano
, p. 5682 - 5690 (2019)
A non-empirical approach for the assignm...
Cyclopalladated ferrocenylimine: a highly effective catalyst for the borylation/suzuki coupling reaction
Ma, Ning,Zhu, Zhiwu,Wu, Yangjie
, p. 4625 - 4629 (2007)
The cyclopalladated ferrocenylimine was ...
Synthesis of DMF-protected Au NPs with different size distributions and their catalytic performance in the Ullmann homocoupling of aryl iodides
Yao, Wang,Gong, Wei-Jie,Li, Hong-Xi,Li, Fei-Long,Gao, Jun,Lang, Jian-Ping
, p. 15752 - 15759 (2014)
DMF-stabilized Au nanoparticles (NPs) wi...
Investigation of the catalytic activity of a Pd/biphenyl-based phosphine system in the Ullmann homocoupling of aryl bromides
Nadri, Shirin,Azadi, Ehsan,Ataei, Ali,Joshaghani, Mohammad,Rafiee, Ezzat
, p. 2966 - 2970 (2011)
We described Ullmann homocoupling promot...
A Bio-Inspired Magnetically Recoverable Palladium Nanocatalyst for the Ullmann Coupling reaction of Aryl halides and Arylboronic acids In Aqueous Media
Dubey, Abhishek V.,Kumar, A. Vijay
, (2020)
Palladium nanoparticles supported on pol...
Microwave assisted efficient protocol for the classic Ullmann homocoupling reaction using Cu-Mg-Al hydrotalcite catalysts
Narasimharao, Katabathini,Al-Sabban, Ebtisam,Saleh, Tamer S.,Gallastegui, Ainara Garcia,Sanfiz, Almudena Celaya,Basahel, Sulaiman,Al-Thabaiti, Shaeel,Alyoubi, Abdulrahman,Obaid, Abdullah,Mokhtar, Mohamed
, p. 152 - 162 (2013)
Four hydrotalcite catalysts containing d...
One-pot two-step stannylation/Stille homocoupling of aryl bromides and iodides under solvent-free conditions
Gribanov, Pavel S.,Golenko, Yulia D.,Topchiy, Maxim A.,Philippova, Anna N.,Kirilenko, Nikita Yu.,Krivoshchapov, Nikolai V.,Sterligov, Grigorii K.,Asachenko, Andrey F.,Bermeshev, Maxim V.,Nechaev, Mikhail S.
, p. 323 - 325 (2018)
A new highly efficient solvent-free meth...
Electrooxidative homo-coupling of arylboronic acids catalyzed by electrogenerated cationic palladium catalysts
Mitsudo, Koichi,Shiraga, Takuya,Tanaka, Hideo
, p. 6593 - 6595 (2008)
An electrochemical method for generating...
Catalytic specificity of linear polystyrene-stabilized Pd nanoparticles during Ullmann coupling reaction in water and the associated mechanism
Ohtaka, Atsushi,Sakon, Akira,Yasui, Asuka,Kawaguchi, Taira,Hamasaka, Go,Uozumi, Yasuhiro,Shinagawa, Tsutomu,Shimomura, Osamu,Nomura, Ry?ki
, p. 87 - 93 (2018)
In the present work, heterogeneous Pd na...
Facile construction of symmetric biaryls using (BeDABCO)2Pd2Cl6 as an efficient and highly active catalyst under microwave irradiation
Hajipour, Abdol Reza,Rafiee, Fatemeh
, p. 147 - 151 (2015)
An efficient catalytic system using (BeD...
High thermal stability and rigid rod of novel organosoluble polyimides and polyamides based on bulky and noncoplanar naphthalene-biphenyldiamine
Liaw, Der-Jang,Chang, Feng-Chyuan,Leung, Man-Kit,Chou, Meng-Yen,Muellen, Klaus
, p. 4024 - 4029 (2005)
The synthesis of a naphthalene-substitut...
PALLADIUM CATALYZED REACTION OF HEXABUTYLDITIN WITH ARYL BROMIDES: PREPARATION OF NEGATIVELY SUBSITUTED ARYLTRIBUTYLTIN
Kosugi, Masanori,Shimizu, Kohji,Ohtani, Atsushi,Migita, Toshihiko
, p. 829 - 830 (1981)
Reaction of hexabutylditin with aryl bro...
Triazoliptycenes: A Twist on Iptycene Chemistry for Regioselective Cross-Coupling to Build Nonstacking Fluorophores
Kang, Taewon,Kim, Hongsik,Lee, Dongwhan
, p. 6380 - 6383 (2017)
Triazoliptycene fluorophores have been d...
Homocoupling of aryl halides promoted by tetrabutylammonium fluoride
Albanese, Domenico,Landini, Dario,Penso, Michele,Petricci, Silvia
, p. 199 - 200 (1999)
The palladium-catalysed homocoupling of ...
Palladium and copper-catalyzed ligand-free coupling of phenylhydrazines in water
Chauhan, Parul,Ravi, Makthala,Singh, Shikha,Raju, Kanumuri S. R.,Bajpai, Vikas,Kumar, Brijesh,Wahajuddin,Yadav, Prem. P.
, p. 43336 - 43340 (2014)
An efficient protocol has been developed...
Zeolite-assisted nitration of biphenyl using nitric acid
Tai, Yanfang,Peng, Xinhua,Shi, Chunjie,Dong, Xiongzi
, p. 867 - 872 (2015)
The nitration process using 95 % nitric ...
Efficient and high turnover homocoupling reaction of aryl iodide by the use of palladacycle catalyst. A convenient way to prepare poly-p-phenylene
Luo, Fen-Tair,Jeevanandam, Arumugasamy,Basu, Manas Kumar
, p. 7939 - 7942 (1998)
Monoiodoarenes undergo reductive couplin...
Pd-Catalyzed desulfitative arylation of olefins by: N -methoxysulfonamide
Ojha, Subhadra,Panda, Niranjan
supporting information, p. 1292 - 1298 (2022/02/19)
A novel Pd-catalyzed protocol for the de...
Palladium-catalyzed aryl group transfer from triarylphosphines to arylboronic acids
Enright, Dale R.,Gogate, Akash R.,Smoliakova, Irina P.,Vasireddy, Purna C. R.
, (2021/11/11)
A study of Pd-catalyzed arylation of ary...
Porphyrin n-pincer pd(Ii)-complexes in water: A base-free and nature-inspired protocol for the oxidative self-coupling of potassium aryltrifluoroborates in open-air
Hanafiah, Marlia M.,Lakkaboyana, Sivarama Krishna,Lakshmidevi, Jangam,Marella, Ravi Kumar,Naidu, Bandameeda Ramesh,Prasad, Sana Siva,Venkateswarlu, Katta
, (2021/09/13)
Metalloporphyrins (and porphyrins) are w...
Pd-catalyzed oxidative homocoupling of arylboronic acids in WEPA: A sustainable access to symmetrical biaryls under added base and ligand-free ambient conditions
Appa, Rama Moorthy,Lakshmidevi, Jangam,Naidu, Bandameeda Ramesh,Venkateswarlu, Katta
, (2021/01/11)
Symmetrical and unsymmetrical biaryls co...
1528-74-1 Process route
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111-34-2,92680-80-3
-butyl vinyl ether
-
-
17763-80-3
para-nitrophenyl triflate
-
-
100-02-7,78813-13-5,89830-32-0
4-nitro-phenol
-
-
1528-74-1
4,4'-dinitrobiphenyl
-
-
101-63-3
bis(4-nitrophenyl)ether
-
-
97826-85-2
(Z)-1-(2-butoxyethenyl)-4-nitrobenzene
-
-
97826-86-3
(E)-1-(2-butoxyethenyl)-4-nitrobenzene
-
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109125-23-7
1-(1-butoxyethenyl)-4-nitrobenzene
| Conditions | Yield |
|---|---|
|
With
triethylamine;
palladium diacetate;
In
N,N-dimethyl-formamide;
at 95 ℃;
for 18h;
Product distribution;
effect of lithium halides and tetrabutyl ammonium halides on cis/trans ratio, and ratio of α- and β-substitution products; var. solvents; other triflates;
|
-
-
100-00-5
4-chlorobenzonitrile
-
-
68-12-2,33513-42-7
N,N-dimethyl-formamide
-
-
1528-74-1
4,4'-dinitrobiphenyl
-
-
100-23-2
N,N-Dimethyl-4-nitroaniline
| Conditions | Yield |
|---|---|
|
With
tetrabutylammomium bromide; triethylamine;
palladium diacetate;
at 115 ℃;
for 72h;
|
17%
77% |
1528-74-1 Upstream products
-
636-98-6
p-nitrobenzene iodide
-
92-52-4
biphenyl
-
92-93-3
1-phenyl-4-nitrobenzene
-
20246-81-5
4,4'-dinitrodiphenic acid
1528-74-1 Downstream products
-
1211-40-1
4-amino-4'-nitrobiphenyl
-
92-87-5
p,p'-diaminobiphenyl
-
1591-30-6
(1,1'-biphenyl)-4,4'-dicarbonitrile
-
7334-13-6
bis-(4'-nitro-biphenyl-4-yl)-diazene-N -oxide
